Comments on: Qcells reaches 28.6% efficiency on full-size tandem perovskite-silicon solar cell /2024/12/qcells-reaches-28-6-efficiency-on-full-size-tandem-perovskite-silicon-solar-cell/ Covering the world of solar power technology, development and installation. Fri, 20 Dec 2024 05:32:26 +0000 hourly 1 https://wordpress.org/?v=6.7.2 By: Solarman2 /2024/12/qcells-reaches-28-6-efficiency-on-full-size-tandem-perovskite-silicon-solar-cell/#comment-148332 Fri, 20 Dec 2024 05:32:26 +0000 /?p=108167#comment-148332 One can make some logical assumptions of what a solar PV cell endures over say 30 + years of daily service. Cordially a crystalline silicon solar cell at an (average) light exposure over 30 years is looking at 8 hours a day and through seasons is approaching an average 8 hours a day of (bright) sunlight. After 30 years of daily use at 8 hours and adding roughly 8 more days for leap years, one gets right at 87,664 sun hours over those 30 years. Borosilicate glass over the cells and doping the cells with boron have helped reduce LeTID for modern cells to 2% degradation the first year of use and about 0.5% for every year after.

Perovskites have specific Achilles heel of oxygen degradation and hydroscopic degredation of the overall crystalline perovskite structure. As such manufacturing processes can introduce voids in the crystalline structure that also degrades light capture. Annealing processes to correct perturbations in the crystalline structure are tantamount to success. Perovskites can be ‘printed’ in thin layers and using different chemical combinations can tune multilayer films for a different band gap of the light spectrum. For instance a Pentiary cell with two Perovskite layers over silicon crystalline cells and two different Perovskite layers behind the silicon crystalline cell could capture front light and back scatter light as a superior bifacial solar PV panel. Long term thermal stresses, LeTID induced crystalline lattice disturbances could allow such an initial superior light capture cell to become the equivalent of an encapsulated silicon cell in an opaque envelope akin to one’s eyes with cataracts. SO, take away, a well known crystalline silicon cell of 22% initial efficiency manufactured today might well have a useful life of 30 + years with a total loss of 2.5% to perhaps 7% efficiency, based on accelerated cell testing performed to generate the typical performance data in panel specification sheets. Perovskite encapsulated silicon cells might degrade in steps over years of use and become much less effective than pure annealed crystalline silicone cells used today. There’s still a LOT of R&D to go for a multilayered solar PV cell that will last 30+ years and still provide broad spectrum light capture and power yields for decades. Just sayin’.

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